Oxidative Addition of a Strained C–C Bond onto Electron-Rich Rhodium(I) at Room Temperature
Journal of the American Chemical Society2013Vol. 135(19), pp. 7142–7145
Citations Over TimeTop 10% of 2013 papers
Abstract
The C-C bond of cyclobutanones undergoes oxidative addition to a T-shape rhodium(I) complex possessing a PBP pincer ligand at room temperature. The remarkable propensity of the rhodium complex for oxidative addition is attributed to the highly electron-donating nature of the boron ligand as well as the unsaturation on the rhodium center.
Related Papers
- → Nickel(II) complexes bearing a pincer ligand containing thioamide units: Comparison between SNS- and SCS-pincer ligands(2010)41 cited
- → Protic- or anionic-NHCs with a classical-NHC in a single [Ru(CNC)(PPh3)2Cl]Cl pincer complex: direct comparison of structure & electronic properties and heterolytic H2 splitting(2024)6 cited
- → Synthesis and Characterization of a Molybdenum Alkylidyne Supported by a Trianionic OCO3– Pincer Ligand(2018)26 cited
- → Dehydrohalogenation of proton responsive complexes: versatile aggregation via pyrazolate pincer ligand arms(2018)18 cited
- → A Ruthenium Hydrido Dinitrogen Core Conserved across Multielectron/Multiproton Changes to the Pincer Ligand Backbone(2018)18 cited