Self-Assembly, Host–Guest Chemistry, and Photophysical Properties of Subphthalocyanine-Based Metallosupramolecular Capsules
Journal of the American Chemical Society2013Vol. 135(28), pp. 10503–10511
Citations Over TimeTop 10% of 2013 papers
Irene Sánchez‐Molina, Bruno Grimm, Rafael M. Krick Calderón, Christian G. Claessens, Dirk M. Guldi, Tomás Torres⊗
Abstract
Four new subphthalocyanine-based capsules have been synthesized and characterized. These supramolecular systems have been successfully employed for the encapsulation of fullerenes and probed by a wide range of characterization methods, including NMR, UV-vis and fluorescence spectroscopy, electrospray ionization mass spectrometry, and electrochemistry. Furthermore, the binding constants of the host guest complexes were estimated. Finally, the photophysical properties revealed that the subphthalocyanines undergo a transduction of singlet excited-state energy to the fullerene inside the cavity upon photoexcitation.
Related Papers
- → Megalo‐Cavitands: Synthesis of Acridane[4]arenes and Formation of Large, Deep Cavitands for Selective C70 Uptake(2022)49 cited
- → Deep Cavitand Calixarene–Solubilized Fullerene as a Potential Photodynamic Agent(2021)19 cited
- → Shape Selectivity of a Metallo Cavitand Host Allows Separation of n‐Alkanes from Isooctane(2021)8 cited
- → Water-soluble resorcin[4]arene: Complexation of anionic aromatic guests by cooperativity of electrostatic and hydrophobic interactions(1999)33 cited
- → Hydrophobic and Metal-Coordinated Confinement Effects Trigger Recognition and Selectivity(2021)13 cited