Organocatalytic C–H/C–H′ Cross-Biaryl Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons
Journal of the American Chemical Society2013Vol. 135(38), pp. 14078–14081
Citations Over TimeTop 10% of 2013 papers
Abstract
The hypervalent iodine-mediated C-C selective coupling of N-methanesulfonyl anilides with aromatic hydrocarbons has been developed. The first organocatalytic oxidative cross-biaryl-coupling was achieved by the catalyst control in defining specific 2,2'-diiodobiphenyls for the direct C-C bond formations.
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