Magnetic Poles Determinations and Robustness of Memory Effect upon Solubilization in a DyIII-Based Single Ion Magnet
Journal of the American Chemical Society2013Vol. 135(44), pp. 16332–16335
Citations Over TimeTop 10% of 2013 papers
Tamyris T. da Cunha, Julie Jung, Marie‐Emmanuelle Boulon, Giulio Campo, Fabrice Pointillart, Cynthia L. M. Pereira, Boris Le Guennic, Olivier Cador, Kévin Bernot, Francesco Pineider, Stéphane Golhen, Lahcène Ouahab
Abstract
The [Dy(tta)3(L)] complex behaves as a single ion magnet both in its crystalline phase and in solution. Experimental and theoretical magnetic anisotropy axes perfectly match and lie along the most electro-negative atoms of the coordination sphere. Both VSM and MCD measurements highlight the robustness of the complex, with persistence of the memory effect even in solution up to 4 K.
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