Surface Structure-Dependent Molecular Oxygen Activation of BiOCl Single-Crystalline Nanosheets
Journal of the American Chemical Society2013Vol. 135(42), pp. 15750–15753
Citations Over TimeTop 1% of 2013 papers
Abstract
We demonstrate that BiOCl single-crystalline nanosheets possess surface structure-dependent molecular oxygen activation properties under UV light. The (001) surface of BiOCl prefers to reduce O2 to ·O2(-) through one-electron transfer, while the (010) surface favors the formation of O2(2-) via two-electron transfer, which is cogoverned by the surface atom exposure and the situ generated oxygen vacancy characteristics of the (001) and (010) surfaces under UV light irradiation.
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