New Powerful and Oxidatively Rugged Dinuclear Ru Water Oxidation Catalyst: Control of Mechanistic Pathways by Tailored Ligand Design
Journal of the American Chemical Society2013Vol. 136(1), pp. 24–27
Citations Over TimeTop 10% of 2013 papers
Abstract
A new powerful and oxidatively rugged pyrazolate-based water oxidation catalyst of formula {[Ru(II)(py-SO3)2(H2O)]2(μ-Mebbp)}(-), 1(H2O)2(-), has been prepared and thoroughly characterized spectroscopically and electrochemically. This new catalyst has been conceived based on a specific ligand tailoring design, so that its performance has been systematically improved. It was also demonstrated how subtle ligand modifications cause a change in the O-O bond formation mechanism, thus revealing the close activation energy barriers associated with each pathway.
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