Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes
Journal of the American Chemical Society2013Vol. 135(50), pp. 18766–18769
Citations Over TimeTop 10% of 2013 papers
Abstract
Monomeric (amino)(carboxy) radicals were synthesized in two steps: the addition of a stable cyclic (alkyl)(amino) carbene to an acyl chloride, followed by a one-electron reduction. Their stability toward dimerization also allows for the synthesis of related bi- and triradicals.
Related Papers
- → A Stable Four-Membered N-Heterocyclic Carbene(2004)139 cited
- → Stabilization of the Elusive 9‐Carbene‐9‐Borafluorene Monoanion(2021)12 cited
- → Bis(carbene) complexes of gold(I) and gold (III)(1973)59 cited
- → ChemInform Abstract: Gold(I)‐Catalyzed Cycloisomerization of Vinylidenecyclopropane‐enes via Carbene or Non‐Carbene Processes.(2016)
- → Carbene Complexes — Complexes with MC Double Bonds(2021)