Stepwise Construction of Discrete Heterometallic Coordination Cages Based on Self-Sorting Strategy
Journal of the American Chemical Society2014Vol. 136(8), pp. 2982–2985
Citations Over TimeTop 10% of 2014 papers
Abstract
A chelation-directed self-sorting synthesis of a series of cationic heterometallic coordination cages (HCCs) with tunable sizes is described. Two complexation modes were found in the cage-forming process. Metal-anchoring host-guest behavior and size-selective in-cage catalytic activities were found for the HCCs.
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