Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis
Journal of the American Chemical Society2014Vol. 136(41), pp. 14345–14348
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Behnaz Ghaffari, Sean Preshlock, Donald L. Plattner, Richard J. Staples, Peter E. Maligres, Shane W. Krska, Robert E. Maleczka, Milton R. Smith
Abstract
Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design.
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