Facile Control of the Charge Density and Photocatalytic Activity of an Anionic Indium Porphyrin Framework via in Situ Metalation

Citations Over TimeTop 10% of 2014 papers

Abstract

An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In(COO)4](-) SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ depending on the M/L ratio during synthesis, resulting in a controllable framework charge density and photocatalytic activity toward the selective oxygenation of sulfides.

Related Papers

• → Synthesis of porphyrin-2,3,12,13- and -2,3,7,8-tetraones: building blocks for the synthesis of extended porphyrin arrays(1995)101 cited
• → Novel aspects of the metalation of heterocycles. Side-chain metalation of thiophen and ring metalation of six-membered nitrogen heterocycles(1974)69 cited
• → Macrocycle Metalation on Solid Surfaces(2018)2 cited
• → Directed Metalation of Arenes with Organolithiums, Lithium Amides, and Superbases(2015)9 cited
• [UV-Vis spectroscopic characterization of LB films of hydroxyl-substituted porphyrin derivatives].(1999)