Simple, Chemoselective, Catalytic Olefin Isomerization
Journal of the American Chemical Society2014Vol. 136(48), pp. 16788–16791
Citations Over TimeTop 10% of 2014 papers
Abstract
Catalytic amounts of Co(Sal(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.
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