Tandem Catalysis of Amines Using Porous Graphene Oxide
Journal of the American Chemical Society2014Vol. 137(2), pp. 685–690
Citations Over TimeTop 10% of 2014 papers
Chenliang Su, Rika Tandiana, Janardhan Balapanuru, Wei Tang, Kapil Pareek, Chang Tai Nai, Tamio Hayashi, Kian Ping Loh
Abstract
Porous graphene oxide can be used as a metal-free catalyst in the presence of air for oxidative coupling of primary amines. Herein, we explore a GO-catalyzed carbon-carbon or/and carbon-heteroatom bond formation strategy to functionalize primary amines in tandem to produce a series of valuable products, i.e., α-aminophosphonates, α-aminonitriles, and polycyclic heterocompounds. Furthermore, when decorated with nano-Pd, the Pd-coated porous graphene oxide can be used as a bifunctional catalyst for tandem oxidation and hydrogenation reactions in the N-alkylation of primary amines, achieving good to excellent yields under mild conditions.
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