Self-Assembly of a 3-D Triply Interlocked Chiral [2]Catenane
Journal of the American Chemical Society2008Vol. 130(10), pp. 2950–2951
Citations Over TimeTop 10% of 2008 papers
Abstract
A tripodal cyclotriveratrylene-based ligand with chelating 2,2‘-bipyridine arms self-assembles with either Zn(NO3)2 or Co(NO3)2 to give 3-D trigonal bipyramidal [M3L2] cage assemblies. These cages triply interlock forming [2]catenane species that have been characterized by mass spectrometry and, in the case of the Zn(II) complex, by X-ray crystallography.
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