Au(I)-Catalyzed Efficient Synthesis of Functionalized Bicyclo[3.2.0]heptanes
Journal of the American Chemical Society2008Vol. 130(22), pp. 6944–6945
Citations Over TimeTop 10% of 2008 papers
Abstract
An efficient Au(I)-catalyzed synthesis of highly strained and functionalized bicyclo[3.2.0]heptanes is developed. Subsequent couplings with various nucleophiles offer additional structural features/complexity. These one-pot, three-component reactions are proposed to proceed via a key 1,3-dipolar cycloaddition between a Au carbenoid-containing carbonyl ylide and ethyl vinyl ether.
Related Papers
- → A Rh(II)-catalyzed cycloaddition approach toward the synthesis of komaroviquinone(2008)39 cited
- → Gold Catalyzed Cyclopropanation/[5+3] Cycloaddition of 1,4,9‐ and 1,4,10‐Allenenynes to Bicyclo[3.3.1]nonane Derivatives(2019)22 cited
- → Intramolecular carbenoid ylide forming reactions of 2-diazo-3-keto-4-phthalimidocarboxylic esters derived from methionine and cysteine(2012)8 cited
- → Use of Rhodium Carbenoid Intermediates for Dipolar Cycloaddition Chemistry(2017)5 cited
- → Cyclization and cycloaddition of 1-cinnamylidene-5-phenyl-3-oxopyrazolidinium ylide(1992)4 cited