Rhodium-Catalyzed Hydroformylation of Cyclopropenes
Journal of the American Chemical Society2008Vol. 130(41), pp. 13804–13809
Citations Over TimeTop 10% of 2008 papers
Abstract
The first catalytic diastereo- and enantioselective hydroformylation of cyclopropenes was demonstrated. The reaction proceeds efficiently under very mild conditions and low catalyst loadings providing high yields of cyclopropylcarboxaldehydes. This novel methodology represents a convenient, atom-economic approach toward optically active cyclopropylcarboxaldehydes from readily available prochiral cyclopropenes.
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