Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles with Nitriles
Journal of the American Chemical Society2008Vol. 130(45), pp. 14972–14974
Citations Over TimeTop 10% of 2008 papers
Abstract
Stable and readily available 1-sulfonyl triazoles are converted to the corresponding imidazoles in good to excellent yields via a rhodium(II)-catalyzed reaction with nitriles. Rhodium iminocarbenoids are proposed intermediates.
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