Homochiral Crystallization of Microporous Framework Materials from Achiral Precursors by Chiral Catalysis
Journal of the American Chemical Society2008Vol. 130(39), pp. 12882–12883
Citations Over TimeTop 1% of 2008 papers
Abstract
While it is not uncommon to form chiral crystals during crystallization, the formation of bulk porous homochiral materials from achiral building units is rare. Reported here is the homochiral crystallization of microporous materials through the chirality induction effect of natural alkaloids. The resulting material possesses permanent microporosity and has a uniform pore size of 9.3 A.
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