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Nickel-Catalyzed Decarbonylative Addition of Anhydrides to Alkynes
Journal of the American Chemical Society2008Vol. 130(51), pp. 17226–17227
Citations Over TimeTop 10% of 2008 papers
Abstract
An intermolecular nickel-catalyzed addition reaction has been developed where phthalic anhydrides react with alkynes to afford substituted isocoumarins. A mechanistic rationale is proposed, implying reductive elimination of Ni(0) promoted by ZnCl(2) cocatalyst as the key step of the catalytic cycle.
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