A Facile One-Pot Synthesis of meso-Aryl-Substituted [14]Triphyrin(2.1.1)
Journal of the American Chemical Society2008Vol. 130(49), pp. 16478–16479
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Zhaoli Xue, Zhen Shen, John Mack, Daiki Kuzuhara, Hiroko Yamada, Tetsuo Okujima, Noboru Ono, Xiao‐Zeng You, Nagao Kobayashi
Abstract
The synthesis and spectroscopic properties of a series of boron-free meso-aryl-substituted [14]triphyrin(2.1.1) compounds containing either peripheral bicyclo[2.2.2]octadiene (BCOD) (2a−c) or benzene rings (3a−c) (aryl = phenyl a, 4-fluorophenyl b, and 4-methylbenzoatephenyl c) are reported. These compounds represent the first examples of free-base contracted porphyrinoids with 14 π-electron aromatic systems containing only the standard pyrrole and isoindoline moieties of the porphyrins and tetrabenzoporphyrins.
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