Selective Fluorogenic and Chromogenic Probe for Detection of Silver Ions and Silver Nanoparticles in Aqueous Media
Journal of the American Chemical Society2009Vol. 131(6), pp. 2040–2041
Citations Over TimeTop 1% of 2009 papers
Amrita Chatterjee, Mithun Santra, Nayoun Won, Sungjee Kim, Jae Kyung Kim, Seung Bin Kim, Kyo Han Ahn
Abstract
A novel rhodamine-based fluorogenic and chromogenic probe for Ag(+) ions in aqueous media is developed, which can be also used for the detection of AgNPs. The sensing mechanism is based on irreversible tandem ring-opening and -forming processes promoted by Ag(+)-coordination to the iodide of the probe, which is accompanied by both color and turn-on type fluorescence changes. The probe shows remarkably high selectivity over other metal ions and detects silver ions up to 14 ppb.
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