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Self-Assembling Fullerenes for Improved Bulk-Heterojunction Photovoltaic Devices
Journal of the American Chemical Society2008Vol. 130(51), pp. 17290–17292
Citations Over TimeTop 10% of 2008 papers
R.D. Kennedy, Alexander L. Ayzner, Darcy D. Wanger, Christopher T Day, Merissa Halim, Saeed I. Khan, Sarah H. Tolbert, Benjamin J. Schwartz, Yves Rubin
Abstract
The fullerene adducts 1a and 1b, whose molecular shapes either promote or hinder the formation of 1-D stacks, have been examined for their potential to form 1-D wire-like domains in bulk-heterojunction organic solar cells. The photovoltaic efficiency of solar cells based on blends of the stacking fullerene 1a with regioregular poly(3-hexylthiophene-2,5-diyl) (P3HT) is greatly enhanced compared to nonstacking model fullerene 1b.
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