Total Synthesis of (−)-Serotobenine
Journal of the American Chemical Society2008Vol. 130(50), pp. 16854–16855
Citations Over TimeTop 10% of 2008 papers
Abstract
The efficient total synthesis of (-)-serotobenine (1) has been achieved by constructing an optically active dihydrobenzofuran ring via a rhodium carbenoid mediated intramolecular C-H insertion reaction, which was developed by our group. Then the possibility of racemization of 1 was investigated using optically active synthetic 1.
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