Carbene-Stabilized Diphosphorus
Journal of the American Chemical Society2008Vol. 130(45), pp. 14970–14971
Citations Over TimeTop 1% of 2008 papers
Yuzhong Wang, Yaoming Xie, Pingrong Wei, R. Bruce King, Henry F. Schaefer, Paul von Ragué Schleyer, Gregory H. Robinson
Abstract
The potassium graphite reduction of L:PCl3 leads to the formation of carbene-stabilized diphosphorus molecules, L:P-P:L, 1 (L: = :C{N(2,6-Pri2C6H3)CH}2) and 2 (L: = :C{N(2,4,6-Me3C6H2)CH}2), respectively. The nature of the bonding in 1 and 2 was delineated by DFT computations.
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