Diversity of Catalysis by an Imido-Hydrido Complex of Molybdenum. Mechanism of Carbonyl Hydrosilylation and Silane Alcoholysis
Journal of the American Chemical Society2008Vol. 131(3), pp. 908–909
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Erik Peterson, Andrey Y. Khalimon, Razvan Simionescu, Л.Г. Кузьмина, Judith A. K. Howard, Georgii I. Nikonov
Abstract
New Imido hydride complex 1 catalyzes a variety of silylation reactions that proceed via initial substrate activation but not silane addition.
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