Mononuclear Copper(II)−Superoxo Complexes that Mimic the Structure and Reactivity of the Active Centers of PHM and DβM
Journal of the American Chemical Society2009Vol. 131(8), pp. 2788–2789
Citations Over TimeTop 10% of 2009 papers
A. Kunishita, Minoru Kubo, Hideki Sugimoto, Takashi Ogura, Kazunobu Sato, Takeji Takui, Shinobu Itoh
Abstract
Mononuclear copper(II)-superoxo complexes 2(X)-OO(*) having triplet (S = 1) ground states were obtained via reaction of O(2) with the copper(I) starting materials 1(X) supported by tridentate ligands L(X) [1-(2-p-X-phenethyl)-5-(2-pyridin-2-ylethyl)-1,5-diazacyclooctane; X = CH(3), H, NO(2)] in various solvents. The superoxo complexes 2(X)-OO(*) mimic the structure [tetrahedral geometry with an end-on (eta(1))-bound O(2)(*-)] and the aliphatic C-H bond activation chemistry of peptidylglycine alpha-hydroxylating monooxygenase and dopamine beta-monooxygenase.
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