A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
Journal of the American Chemical Society2009Vol. 131(13), pp. 4570–4571
Citations Over TimeTop 1% of 2009 papers
Fernando J. Uribe‐Romo, Joseph R. Hunt, Hiroyasu Furukawa, Cornelius Klöck, M. O’Keeffe, Omar M. Yaghi
Abstract
A new crystalline porous three-dimensional covalent organic framework, termed COF-300, has been synthesized and structurally characterized. Tetrahedral tetra-(4-anilyl)-methane and linear terephthaldehyde building blocks were condensed to form imine linkages in a material whose X-ray crystal structure shows five independent diamond frameworks. Despite the interpenetration, the structure has pores of 7.2 A diameter. Thus, COF-300 shows thermal stability up to 490 degrees C and permanent porosity with a surface area of 1360 m(2) g(-1).
Related Papers
- → Imine and imine-derived linkages in two-dimensional covalent organic frameworks(2022)350 cited
- → A dynamic covalent imine gel as a luminescent sensor(2014)59 cited
- → Promoting charge separation by rational integration of a covalent organic framework on a BiVO4 photoanode(2022)20 cited
- → Morphology controlled synthesis of octahedral covalent imine frameworks through acid modulated aldehyde-amine polycondensation(2016)15 cited
- → Macromolecular Rapid Communications(2006)578 cited