Nickel-Catalyzed Decarboxylative Carboamination of Alkynes with Isatoic Anhydrides
Journal of the American Chemical Society2009Vol. 131(22), pp. 7494–7495
Citations Over TimeTop 10% of 2009 papers
Abstract
An intermolecular nickel-catalyzed addition reaction in which isatoic anhydrides react with alkynes to afford substituted quinolones has been developed. A mechanistic rationale is proposed, implying oxidative addition of Ni(0) to a carbamate, which allows intermolecular addition to alkynes via decarboxylation.
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