Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows
Journal of the American Chemical Society2009Vol. 131(26), pp. 9186–9188
Citations Over TimeTop 1% of 2009 papers
Abstract
Reactions between two novel hexatopic carboxylate ligands and copper salts give rise to two isostructural metal-organic frameworks (MOFs) with a (3,24)-connected network topology containing both micro- and mesocavities with sizes of up to 3 nm. Both frameworks retain their porosity after guest-molecule removal, leading to high surface areas. Constructing MOFs containing mesocavities with microwindows may serve as a general approach toward stable MOFs with high surface areas.
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