Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation
Journal of the American Chemical Society2009Vol. 131(25), pp. 8730–8731
Citations Over TimeTop 1% of 2009 papers
Jonathan F. Hull, David Balcells, James D. Blakemore, Christopher D. Incarvito, Odile Eisenstein, Gary W. Brudvig, Robert H. Crabtree
Abstract
A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.
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