Unraveling Atomic Positions in an Oxide Spinel with Two Jahn−Teller Ions: Local Structure Investigation of CuMn₂O₄

Citations Over TimeTop 10% of 2009 papers

Abstract

At first sight, the quenched tetragonal spinel CuMn(2)O(4) can be formulated with Cu(2+) and Mn(3+), implying that the tetrahedral site is Jahn-Teller (JT)-active Cu(2+) and the octahedral site is JT-active Mn(3+). High-resolution, high-momentum-transfer neutron scattering analysis suggests that the sample has approximately 30% inversion: Mn on the tetrahedral Cu site with compensating Cu on the octahedral site. Reverse Monte Carlo (RMC) analysis of the pair distribution function allows details of metal-oxygen connectivity to be probed in a manner that is significantly on the local rather than the average scale. Bond valence analysis of the RMC supercell reveals that both JT ions disproportionate to higher and lower valence states as a means of avoiding their JT tendency, particularly on the tetrahedral site. The occurrence of Cu(3+) in particular is suggested for the first time and is supported by X-ray photoelectron spectroscopy data. The bimodal distribution of O-Cu-O bond angles at the tetrahedral site (distinct from what is seen for O-Mn-O bond angles) further reveals a hidden distinction between sites previously considered to be equivalent. Application of total scattering techniques originally developed for highly disordered materials permits the examination of nanoscale crystalline structure with elemental specificity that is not available in traditional reciprocal-space analysis.

Related Papers

• → Probing structural relaxation in nanosized catalysts by combining EXAFS and reverse Monte Carlo methods(2016)44 cited
• → Determination of partial pair distribution functions in amorphous Ge15Te85 by simultaneous RMC simulation of diffraction and EXAFS data(2007)30 cited
• → Reverse Monte Carlo simulations of an amorphous Se0.90S0.10 alloy produced by mechanical alloying combining XRD and EXAFS data(2010)8 cited
• → Micro Reverse Monte Carlo Approach to EXAFS Analysis(2014)6 cited
• → EXAFS, XRD and RMC studies of an Amorphous Ga$_{50}$Se$_{50}$ Alloy Produced by Mechanical Alloying(2003)