Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes
Journal of the American Chemical Society2009Vol. 131(40), pp. 14168–14169
Citations Over TimeTop 1% of 2009 papers
Abstract
Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst. Potassium formate was obtained with turnover numbers up to 3,500,000 and a turnover frequency of 150,000 h(-1), both of which are the highest values reported to date.
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