Multiroute Synthesis of Porous Anionic Frameworks and Size-Tunable Extraframework Organic Cation-Controlled Gas Sorption Properties

Citations Over TimeTop 1% of 2009 papers

Abstract

Under diverse and dramatically different chemical environments, including organic solvents, an ionic liquid, and a deep eutectic solvent, a series of porous anionic framework materials that contain size-tunable, ion-exchangeable extraframework organic cations have been prepared. Even though a large fraction of the pore space is occupied with charge-balancing cations, some of these materials exhibit a very high gas uptake capacity (e.g., 70.6 cm(3)/g for CO(2) at 1 atm and 273 K), suggesting that the charged anionic framework and extraframework cations may help to enhance the gas adsorption.

Related Papers

• → Co-sorption of ofloxacin and Cu(II) in soils before and after organic matter removal(2014)42 cited
• [Sorption behaviors of BDE-28 on natural soils].(2011)
• Studies on the Sorption Characteristics of $^{137}Cs$ onto Granite and Tuff(1995)
• THE INFLUENCE OF CONTAINER WALL SORPTION ON SORPTION RATIO OF ￣(241)AM(1994)
• Sorption Characteristics of BDE-47 on Natural Soils(2011)