Rhodium and Iridium Amido Complexes Supported by Silyl Pincer Ligation: Ammonia N−H Bond Activation by a [PSiP]Ir Complex
Journal of the American Chemical Society2009Vol. 131(40), pp. 14234–14236
Citations Over TimeTop 10% of 2009 papers
Abstract
Ir silyl pincer complexes insert into the N-H bonds of anilines and ammonia under mild conditions to form isolable [Cy-PSiP]Ir(H)(NHR) complexes that are resistant to N-H bond reductive elimination at room temperature, even in the presence of arenes, alkenes, and phosphines.
Related Papers
- → An unprecedented, figure-of-eight, dinuclear iridium(i) dicarbene and new iridium(iii) ‘pincer’ complexes(2008)79 cited
- → Tricyclohexylphosphine complexes of rhodium(I), rhodium(II), iridium(I) and iridium(III)(1973)37 cited
- → Rhodium(I)- and iridium(I)-diethyldithiocarbamatoalkene complexes and their use in the preparation of rhodium(III)- and iridium(III)-diethyldithiocarbamato complexes(1974)19 cited
- → Sequential spectrophotometric determination of rhodium and iridium with 1,5-diphenylcarbazide(1984)7 cited