Remarkably Stable Chalcogen(II) Dications
Journal of the American Chemical Society2009Vol. 131(42), pp. 15126–15127
Citations Over TimeTop 11% of 2009 papers
Abstract
Air-stable, chalcogen-centered dications have been synthesized and comprehensively characterized. These represent the first diiminopyridine (DIMPY) complexes of the chalcogens as well as the single nonmetallic (sulfur) complex of this ubiquitous ligand. Their stability under ambient conditions is a distinct contrast to other highly charged main-group cations.
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