Rhodium-Catalyzed Enantioselective Cyclopropanation of Olefins withN-Sulfonyl 1,2,3-Triazoles
Journal of the American Chemical Society2009Vol. 131(50), pp. 18034–18035
Citations Over TimeTop 10% of 2009 papers
Abstract
N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.