Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity
Journal of the American Chemical Society2010Vol. 132(8), pp. 2561–2563
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Ming‐Hua Zeng, Qiang-xin Wang, Yan‐Xi Tan, Sheng Hu, Hai‐Xia Zhao, La‐Sheng Long, Mohamedally Kurmoo
Abstract
A highly stable pillared and double-walled zinc(II) metal-organic framework with regular nanochannels displays single-crystal to single-crystal transformation upon desolvation and a large quantity of iodine uptake, controlled release, and electrical conductivity elevation due to synergy between the iodine guests and the host framework.
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