Palladium(II)-Catalyzed Oxidative C−H/C−H Cross-Coupling of Heteroarenes
Journal of the American Chemical Society2010Vol. 132(6), pp. 1822–1824
Citations Over TimeTop 1% of 2010 papers
Abstract
An efficient methodology for the synthesis of unsymmetrical biheteroaryl molecules has been developed via Pd(II)-catalyzed oxidative C−H/C−H cross-coupling of heteroarenes. An inversion in reactivity and selectivity has been achieved successfully to perform the desired heterocoupling. This process allows the heterocoupling of not only electron-rich N-containing heteroarenes (e.g., xanthines, azoles, and indolizines) but also electron-poor pyridine N-oxides with various thiophenes or furans.
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