A Broadly Applicable Method for the Efficient Synthesis of α-O-Linked Glycopeptides and Clustered Sialic Acid Residues
Journal of the American Chemical Society1999Vol. 121(12), pp. 2662–2673
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Jacob B. Schwarz, Scott D. Kuduk, Xiaotao Chen, Dalibor Sameš, Peter W. Glunz, Samuel J. Danishefsky
Abstract
The total syntheses of complex sialylated cell-surface antigens have been accomplished. The target systems include 2,3-STF, STn, 2,6-STF, and glycophorin antigens. In addition, an α-O-linked serine glycoside of an entire Lewis blood group (Y) antigen has been assembled.
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