Titanium(II)-Mediated Asymmetric Intramolecular Cyclization of 2,7- and 2,8-Enynyl Chiral Acetals. Synthetic Equivalent of Stoichiometric Intramolecular Asymmetric Metallo-Ene Reaction

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Abstract

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationTitanium(II)-Mediated Asymmetric Intramolecular Cyclization of 2,7- and 2,8-Enynyl Chiral Acetals. Synthetic Equivalent of Stoichiometric Intramolecular Asymmetric Metallo-Ene ReactionYuuki Takayama, Sentaro Okamoto, and Fumie SatoView Author Information Department of Biomolecular Engineering Tokyo Institute of Technology 4259 Nagatsuta-cho, Midori-ku Yokohama, Kanagawa 226-8501, Japan Cite this: J. Am. Chem. Soc. 1999, 121, 14, 3559–3560Publication Date (Web):March 30, 1999Publication History Received4 January 1999Published online30 March 1999Published inissue 1 April 1999https://pubs.acs.org/doi/10.1021/ja990021xhttps://doi.org/10.1021/ja990021xrapid-communicationACS PublicationsCopyright © 1999 American Chemical SocietyRequest reuse permissionsArticle Views440Altmetric-Citations38LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Aldehydes,Cyclization,Ethers,Reaction products,Stereochemistry Get e-Alerts

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