Site Preferences in the Mixed Cation Zeolite, Li,Na-Chabazite: A Combined Solid-State NMR and Neutron Diffraction Study | doi.page

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Site Preferences in the Mixed Cation Zeolite, Li,Na-Chabazite: A Combined Solid-State NMR and Neutron Diffraction Study

Journal of the American Chemical Society2000Vol. 122(8), pp. 1700–1708

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Luis J. Smith, Hellmut Eckert, Anthony K. Cheetham

Abstract

The locations of Li+ and Na+ cations in dehydrated chabazite were studied by neutron powder diffraction, 7Li and 23Na magic-angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy, and 23Na multiple quantum MAS (MQMAS) NMR spectroscopy. Neutron powder diffraction data were collected on lithium chabazite (space group: R3̄m, a = 9.3357(5) Å, α = 93.482(4)°, Rwp = 5.83%, Rp = 4.65%, χ2 = 1.24) and on a mixed lithium sodium chabazite (space group: R3̄m, a = 9.3385(5) Å, α = 93.382(4)°, Rwp = 5.94%, Rp = 4.83%, χ2 = 1.27). Both neutron diffraction and 7Li MAS reveal lithium chabazite to have two cationic sites: one at the six-ring window of the hexagonal prism (SII) and one in the supercage at the four-ring window of the hexagonal prism (SIII). Mixed lithium−sodium chabazites reveal strong evidence of selective occupancy accompanied by concomitant rearrangement effects. While the introduction of sodium into lithium chabazite reduces occupation primarily at the SIII site, a decrease of the SII site lithium cation population is also observed at sodium levels above 24%. At low sodium content, sodium cations occupy a site in the eight-ring window of the channel (SIII'). At sodium content around 70% and higher, sodium cations also reside at the SII sites vacated by the lithium cations. The increased population of SII sites by Na+ is associated with a marked increase in the lattice constant. The implications of the observed site preferences for noncryogenic air separation are discussed.

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Abstract

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