Realizing 17.5% Efficiency Flexible Organic Solar Cells via Atomic-Level Chemical Welding of Silver Nanowire Electrodes

Citations Over TimeTop 1% of 2022 papers

Abstract

Solution processable flexible transparent electrodes (FTEs) are urgently needed to boost the efficiency and mechanical stability of flexible organic solar cells (OSCs) on a large scale. However, how to balance the optoelectronic properties and meanwhile achieve robust mechanical behavior of FTEs is still a huge challenge. Silver nanowire (AgNW) electrodes, exhibiting easily tuned optoelectronic/mechanical properties, are attracting considerable attention, but their poor contacts at the junction site of the AgNWs increase the sheet resistance and reduce mechanical stability. In this study, an ionic liquid (IL)-type reducing agent containing Cl- and a dihydroxyl group was employed to control the reduction process of silver (Ag) in AgNW-based FTEs precisely. The Cl- in the IL regulates the Ag+ concentration through the formation and dissolution of AgCl, whereas the dihydroxyl group slowly reduces the released Ag+ to form metal Ag. The reduced Ag grew in situ at the junction site of the AgNWs in a twin-crystal growth mode, facilitating an atomic-level contact between the AgNWs and the reduced Ag. This enforced atomic-level contact decreased the sheet resistance, and enhanced the mechanical stability of the FTEs. As a result, the single-junction flexible OSCs based on this chemically welded FTE achieved record power conversion efficiencies of 17.52% (active area: 0.062 cm2) and 15.82% (active area: 1.0 cm2). These flexible devices also displayed robust bending and peeling durability even under extreme test conditions.

Related Papers

• → Dye-sensitized solar cells based on multilayered ultrafine TiO2 nanowire photoanodes(2014)7 cited
• → A solution-processed small molecule with optimal side chains for high efficiency non-fullerene organic solar cells(2018)11 cited
• → Organic photovoltaics based on solution-processed benzoporphyrin(2007)9 cited
• → Determination of contact and intrinsic nanowire resistivity in two-contact ZnO nanowire devices(2008)
• → Transmission electron microscopy of high threshold voltage, high contact resistance, and high sheet resistance of MOS device(2002)