Ligand-Enabled Pd(II)-Catalyzed Bromination and Iodination of C(sp3)–H Bonds
Journal of the American Chemical Society2017Vol. 139(16), pp. 5724–5727
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Ru‐Yi Zhu, Tyler G. St. Denis, Ying Shao, Jian He, Joshua D. Sieber, Chris H. Senanayake, Jin‐Quan Yu
Abstract
We herein report the palladium(II)-catalyzed bromination and iodination of a variety of α-hydrogen-containing carboxylic acid and amino acid-derived amides. These reactions are exclusively enabled by quinoline-type ligands. The halogenated products obtained in this reaction are highly versatile and rapidly undergo further diversification. Further, we report the first example of a free carboxylic acid-directed Pd(II)-catalyzed C(sp3)-H bromination, enabled by quinoline ligands.
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