Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity
Journal of the American Chemical Society2018Vol. 140(44), pp. 14571–14575
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Arnaud Chaix, Georges Mouchaham, Aleksander Shkurenko, Phuong Mai Hoang, Basem Moosa, Prashant M. Bhatt, Karim Adil, K. Saláma, Mohamed Eddaoudi, Niveen M. Khashab
Abstract
Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO2. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO2/CH4 separation for natural gas upgrading.
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