Total Vapor Pressure Measurements for 2-Ethoxyethanol with Carbon Tetrachloride, Chloroform, and Dichloromethane at 303.15 K

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Abstract

Total pressure measurements are reported for the binary mixtures of 2-ethoxyethanol with carbon tetrachloride, chloroform, and dichloromethane at 303.15 K. The data were obtained using a Van Ness type apparatus and were fitted with a modified Margules equation using Barker's method. The total pressure data are represented by the model to within an average absolute deviation of approximately 0.06 kPa. Solutions of 2-ethoxyethanol with carbon tetrachloride show positive deviations from ideality, while those of 2-ethoxyethanol with chloroform and with dichloromethane show negative deviations at low chloroalkane mole fraction and positive deviations at high chloroalkane concentration.

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