Investigations of the Reaction Mechanisms of 1,2-Indanediones with Amino Acids
The Journal of Organic Chemistry2001Vol. 66(23), pp. 7666–7675
Citations Over TimeTop 10% of 2001 papers
Abstract
The reaction mechanisms of amino acids with a new class of fluorogenic reagents were investigated. The structures of colored and fluorescent species formed in these reactions were partially confirmed by experimental evidence. Reaction intermediates, C-N-C 1,3-dipoles derived from imines, were trapped with dipolarophiles in 3 + 2 cycloadditions to form spiropyrrolidines.
Related Papers
- → Probing the Reaction Mechanism of CO2 Electroreduction over Ag Films via Operando Infrared Spectroscopy(2016)539 cited
- → How to scrutinize adsorbed intermediates observed by in situ spectroscopy: Analysis of Coverage Transients (ACT)(2020)28 cited
- → Reaction Mechanism of Pd‐Catalyzed “CO‐Free” Carbonylation Reaction Uncovered by In Situ Spectroscopy: The Formyl Mechanism(2020)17 cited
- → DFT Research on the Dehydroxylation Reaction of Pyrophyllite 2. Characterization of Reactants, Intermediates, And Transition States along the Reaction Path(2008)18 cited
- → Reaction Mechanism of Pd‐Catalyzed “CO‐Free” Carbonylation Reaction Uncovered by In Situ Spectroscopy: The Formyl Mechanism(2020)4 cited