Palladium-Catalyzed Arylation of Allylic Benzoates Using Hypervalent Siloxane Derivatives
The Journal of Organic Chemistry2001Vol. 66(21), pp. 7159–7165
Citations Over TimeTop 10% of 2001 papers
Abstract
Palladium-catalyzed cross-coupling of hypervalent arylsiloxane derivatives proceeded in good to excellent yields with allylic benzoates. Arylation occurred with complete inversion of configuration. The scope and limitations of this reaction, an alternative to the Stille coupling, is summarized.
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