Introduction of Functionalized C1, C2, and C3 Units to Imines through the Dimethylzinc−Air-Initiated Radical Addition
The Journal of Organic Chemistry2004Vol. 69(5), pp. 1531–1534
Citations Over TimeTop 10% of 2004 papers
Abstract
Introduction of functionalized C1, C2, and C3 units to imines was achieved by using the dimethylzinc-air-initiated alpha-alkoxyalkyl radical addition as a key reaction. The addition to a C[double bond]N double bond chemoselectively occurred in the presence of a C[double bond]O double bond, which is one of the advantages of this radical addition reaction over ionic addition reactions.
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