Reactions of a Carbamoylstannane with Acid Chlorides: Highly Efficient Synthesis of α-Oxo Amides
The Journal of Organic Chemistry2004Vol. 69(3), pp. 974–976
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Abstract
Treatment of acid chlorides with a carbamoylstannane under mild conditions (mostly rt for a few hours) affords alpha-oxo amides in high yields. Vicinal polycarbonyl compounds are also obtained, although spontaneous decarbonylation occasionally occurs.
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