A Photochemical Approach to the Galanthan Ring System
The Journal of Organic Chemistry2004Vol. 69(5), pp. 1603–1606
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Abstract
A five-step, atom-efficient synthesis of the Galanthan tetracyclic skeleton has been developed. The key step is an unusual intramolecular de Mayo reaction using an isocarbostyril substrate with a functionalized tether on nitrogen. The target molecule is produced in 35% overall yield from isocarbostyril.
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