Microwave-Promoted Suzuki Reactions of Aryl Chlorides in Aqueous Media
The Journal of Organic Chemistry2005Vol. 70(6), pp. 2332–2334
Citations Over TimeTop 10% of 2005 papers
Abstract
[reaction: see text] The microwave-promoted Suzuki coupling reaction of aryl chlorides with boronic acids performed in an aqueous media was studied using the air- and moisture-stable catalyst POPd2 (dihydrogen di-mu-chlorodichlorobis(di-tert-butylphosphinito-kappaP)dipalladate (2-)). This catalyst system under microwave conditions (150 degrees C, 15 min) provided coupled products with yields ranging from 64% to 99%. This method tolerated a variety of substituents and sterically hindered substrates.
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